
Titanium’s most useful properties of the metal form are corrosion
resistance, and the highest strength-to-weight ratio of any
metal. In its unalloyed condition, titanium is as strong as
some steels, but 45% lighter. There are two allotropic forms
and five naturally occurring isotopes of this element; Ti through
Ti, with Ti being the most abundant (73.8%). Titanium's properties
are chemically and physically similar to zirconium.
A metallic element, titanium is recognized for its high strength-to-weight
ratio. It is a strong metal with low density that is quite
ductile (especially in an oxygen-free environment), lustrous,
and metallic-white in color. The relatively high melting point
(over 1,649 °C or 3,000 °F) makes it useful as a
refractory metal.
Commercial (99.2% pure) grades of titanium have ultimate tensile
strength of about 63,000 psi (434 MPa), equal to
that of some steel alloys, but are 45% lighter. Titanium is
60% more dense than aluminium, but more than twice as strong
as the most commonly used 6061-T6 aluminium alloy. Titanium
can be used for multiple reasons. Certain titanium alloys (e.g.,
Beta C) achieve tensile strengths of over 200,000 psi
(1380 MPa). However, titanium loses strength when heated
above 430 °C (800 °F).
It is fairly hard although not as hard as some grades of heat-treated
steel, non-magnetic and a poor conductor of heat and electricity.
Machining requires precautions, as the material will soften
and gall if sharp tools and proper cooling methods are not
used. Like those made from steel, titanium structures have
a fatigue limit which guarantees longevity in some applications.
The metal is a dimorphic allotrope with the hexagonal alpha
form changing into the body-centered cubic (lattice) beta form
at 882 °C (1,619 °F). The specific heat of the alpha
form increases dramatically as it is heated to this transition
temperature but then falls and remains fairly constant for
the beta form regardless of temperature. Similar to zirconium
and hafnium, an additional omega phase exists, which is thermodynamically
stable at high pressures, but which may exist metastably at
ambient pressures. This phase is usually hexagonal (ideal)
or trigonal (distorted) and can be viewed as being due to a
soft longitudinal acoustic phonon of the beta phase causing
collapse of (111) planes of atoms.
Applications
Titanium is used in steel as an alloying element (ferro-titanium)
to reduce grain size and as a deoxidizer, and in stainless
steel to reduce carbon content. Titanium is often alloyed with
aluminium (to refine grain size), vanadium, copper (to harden),
iron, manganese, molybdenum, and with other metals. Applications
for titanium mill products (sheet, plate, bar, wire, forgings,
castings) can be found in industrial, aerospace, recreational,
and emerging markets. Powdered titanium is used in pyrotechnics
as a source of bright-burning particles.
Aerospace
and marine
Due to its high corrosion resistance to sea water, titanium
is used to make propeller shafts and rigging and in the heat
exchangers of desalination plants; in heater-chillers for salt
water aquariums, fishing line and leader, and for divers' knives.
Titanium is used to manufacture the housings and other components
of ocean-deployed surveillance and monitoring devices for scientific
and military use. The former Soviet Union developed techniques
for making submarines largely out of titanium, which became
both the fastest and deepest diving submarines of their time.
Titanium commercial aerospace requirements (including engine
components such as blades, discs, rings and engine cases as
well as airframe components including bulkheads, tail sections,
landing gear, wing supports and fasteners) can account for
a substantial proportion of the mass of modern aircraft.
Industrial
Welded titanium pipe and process equipment (heat exchangers,
tanks, process vessels, valves) are used in the chemical and
petrochemical industries primarily for corrosion resistance.
Specific alloys are used in downhole and nickel hydrometallurgy
applications due to their high strength titanium Beta C, corrosion
resistance, or combination of both. The pulp and paper industry
uses titanium in process equipment exposed to corrosive media
such as sodium hypochlorite or wet chlorine gas (in the bleachery).
Other applications include: ultrasonic welding, wave soldering,
and sputtering targets.
Consumer
and architectural
Titanium metal is used in automotive applications, particularly
in automobile or motorcycle racing, where weight reduction
is critical while maintaining high strength and rigidity. The
metal is generally too expensive to make it marketable to the
general consumer market, other than high-end products, particularly
for the racing/performance market. Late model Corvettes have
been available with titanium exhausts.
The Guggenheim Museum Bilbao is sheathed in titanium panels.
Titanium is used in many sporting goods: tennis rackets, golf
clubs, lacrosse stick shafts; cricket, hockey, lacrosse,
and football helmet grills; and bicycle frames and components.Titanium
alloys are also used in spectacle frames. This results in
a rather expensive, but highly durable and long lasting frame
which is light in weight and causes no skin allergies. Many
backpackers use titanium equipment, including cookware, eating
utensils, lanterns, and tent stakes. Though slightly more
expensive than traditional steel or aluminium alternatives,
these titanium products can be significantly lighter without
compromising strength. Titanium is also favored for use by
farriers, since it is lighter and more durable than steel
when formed into horseshoes.
Because of its durability, titanium has become more popular
for designer jewelry. Its inertness makes it a good choice
for those with allergies or those who will be wearing the jewelry
in environments such as swimming pools. Titanium's durability,
light weight, dent- and corrosion- resistance makes it useful
in the production of watch cases.
A number of artists work with titanium to produce artworks
such as sculptures, decorative objects and furniture.
Due to its superior strength and light weight when compared
to other metals traditionally used in firearms (steel, stainless
steel, and aluminium), and advances in metal-working techniques,
the use of titanium has become more widespread in the manufacture
of firearms. Primary uses include pistol frames and revolver
cylinders.
Medical
This left lateral cephalametric radiograph shows a profile
of the human skull. A fracture of the eye socket was repaired
by stabilizing the fractured bones with small titanium plates
and screws.Because it is biocompatible (non-toxic and is not
rejected by the body), titanium is used in a gamut of medical
applications including surgical implements and implants, such
as hip balls and sockets (joint replacement) that can stay
in place for up to 20 years. Titanium has the inherent property
to osseointegrate, enabling use in dental implants that can
remain in place for over 30 years. This property is also useful
for orthopedic implant applications.Since titanium is non-ferromagnetic,
patients with titanium implants can be safely examined with
magnetic resonance imaging (convenient for long-term implants).
Preparing titanium for implantation in the body involves subjecting
it to a high-temperature plasma arc which removes the surface
atoms, exposing fresh titanium that is instantly oxidized.
Titanium is also used for the surgical instruments used in
image-guided surgery, as well as wheelchairs, crutches, and
any other products where high strength and low weight are desirable.
Its inertness and ability to be attractively colored makes
it a popular metal for use in body piercing. Titanium may be
anodized to produce various colors.
Precautions
Nettle contains up to 80 parts per million of titanium
Titanium is non-toxic even in large doses and does not play
any natural role inside the human body. An estimated 0.8
milligrams of titanium is ingested by humans each day but
most passes through without being absorbed. It does, however,
have a tendency to bio-accumulate in tissues that contain
silica. An unknown mechanism in plants may use titanium to
stimulate the production of carbohydrates and encourage growth.
This may explain why most plants contain about 1 part
per million (ppm) of titanium, food plants have about 2 ppm,
and horsetail and nettle contain up to 80 ppm.
As a powder or in the form of metal shavings, titanium metal
poses a significant fire hazard and, when heated in air, an
explosion hazard. Water and carbon dioxide-based methods to
extinguish fires are ineffective on burning titanium; Class
D dry powder fire fighting agents must be used instead.
When used in the production or handling of chlorine, care must
be taken to use titanium only in locations where it will not
be exposed to dry chlorine gas which can result in a titanium/chlorine
fire. A fire hazard exists even when titanium is used in wet
chlorine due to possible unexpected drying brought about by
extreme weather conditions.
Titanium can catch fire when a fresh, non-oxidized surface
comes in contact with liquid oxygen. Such surfaces can appear
when the oxidized surface is struck with a hard object, or
when a mechanical strain causes the emergence of a crack. This
poses the possible limitation for its use in liquid oxygen
systems, such as those found in the aerospace industry.