
Nickel is a silvery-white metal with a slight golden tinge
that takes a high polish. It is one of only four elements
that are magnetic at or near room temperature. It belongs
to the transition metals and is hard and ductile. It occurs
most often in combination with sulfur and iron in pentlandite,
with sulfur in millerite, with arsenic in the mineral nickeline,
and with arsenic and sulfur in nickel galena. Nickel is commonly
found in iron meteorites as the alloys kamacite and taenite.
Similar to the elements chromium, aluminium and titanium, nickel
is a very reactive element, but is slow to react in air at
normal temperatures and pressures. Due to its permanence in
air and its slow rate of oxidation, it is used in coins, for
plating metals such as iron and brass, for chemical apparatus,
and in certain alloys such as German silver.
Nickel is chiefly valuable for the alloys it forms, especially
many superalloys, and particularly stainless steel. Nickel
is also a naturally magnetostrictive material, meaning that
in the presence of a magnetic field, the material undergoes
a small change in length. In the case of Nickel, this change
in length is negative (contraction of the material), which
is known as negative magnetostriction.
The most common oxidation state of nickel is +2 with several
Ni complexes known. It is also thought that a +6 oxidation
state may exist, however, this has not been demonstrated conclusively.
The unit cell of nickel is a face centered cube with a lattice
parameter of 0.352 nm giving a radius of the atom of 0.125
nm.
Applications
Nickel superalloy jet engine (RB199) turbine blade
Nickel is used in many industrial and consumer products, including
stainless steel, magnets, coinage, rechargeable batteries,
electric guitar strings and special alloys. It is also used
for plating and as a green tint in glass. Nickel is pre-eminently
an alloy metal, and its chief use is in the nickel steels
and nickel cast irons, of which there are many varieties.
It is also widely used in many other alloys, such as nickel
brasses and bronzes, and alloys with copper, chromium, aluminium,
lead, cobalt, silver, and gold.
The amounts of nickel used for various applications are 60%
used for making nickel steels, 14% used in nickel-copper alloys
and nickel silver, 9% used to make malleable nickel, nickel
clad, Inconel and other superalloys, 6% used in plating, 3%
use for nickel cast irons, 3% in heat and electric resistance
alloys, such as Nichrome, 2% used for nickel brasses and bronzes
with the remaining 3% of the nickel consumption in all other
applications combined. In the laboratory, nickel is frequently
used as a catalyst for hydrogenation, most often using Raney
nickel, a finely divided form of the metal alloyed with aluminium
which adsorbs hydrogen gas. Nickel is often used in coins,
or occasionally as a substitute for decorative silver. The
American 'nickel' five-cent coin is 75% copper and 25% nickel.
The Canadian nickel minted at various periods between 1922-81
was 99.9% nickel, and was magnetic. Various other nations have
historically used and still use nickel in their coinage.